High-performance anti-static additive for electrically conductive and reinforced natural rubber (NR) and butadiene rubber (BR)


TUBALL™ graphene nanotubes impart the required conductivity and enhance the mechanical properties of blends of butadiene rubber (BR) and natural rubber (NR) based on mineral fillers, while not impacting elasticity or softness, and allowing for colored compounds. 

When introduced into rubbers, even at concentrations as low as a tenth of a percent of the total weight of the material, graphene nanotubes (or single wall carbon nanotubes) create a reinforcing conductive network, thus making it possible to achieve a previously unobtainable combination of properties. This sets graphene nanotubes apart from other conductive fillers, such as multi wall carbon nanotubes, carbon black, silver- and nickel-coated graphite, and polymer-based additives, which lead to negative trade-offs in flexibility, elasticity, or a high price.

Graphene nanotubes in NR/BR blend of rubbers and mineral fillers are the ideal choice for non-marking solid tires. They are used in a number of specific cases, such as when the tire is used in potentially explosive areas that are strictly regulated by the ATEX and other international standards. Moreover, the new electrostatic requirements of the EN 1755 standard now consider ignition risk during “normal” operation, thus obliging many industries, such as chemical, pharmaceutical, food & drink, waste, cosmetics, military, manufacturing, logistics, and others, to comply with the requirements of high surface resistance for the outer material of castors and wheels.


  • Non-marking solid tires: add nanotubes to meet ESD standards

  • How can you avoid carbon dust at compounding plants?


Using graphene nanotubes as an alternative solution to provide the required conductive properties as well as maintain color and basic formulation properties of non-marking solid tires makes it possible to achieve numerous target properties. High mechanical strength and conductivity in compliance with international standards make these tires indispensable in many industries where ESD protection and static dissipative properties are required, including potentially explosive areas: in oil & gas, mining, electronics manufacturing, and other fields.

TEST RESULTS: MECHANICAL PROPERTIES

Volume resistivity

Surface resistivity

SIMCO ST-4

EN 60079

3 wt.% TUBALL™ MATRIX 618 beta

3.5 × 102 Ω·cm

5 × 105 Ω/sq

1.6 × 105 Ω

4.4 wt.% TUBALL™ MATRIX 620 

4.2 × 102 Ω·cm

5.2 × 105 Ω/sq

9.5 × 104 Ω



To simplify the use of nanotubes, OCSiAl has developed TUBALL™ MATRIX concentrate for non-marking anti-static NR/BR compounds, which is compatible with a wide range of rubber polymer grades. Its application does not require any additional equipment or changes in technological processes. 

TUBALL™ MATRIX for anti-static NR/BR rubber features: 

  • Permanent, stable electrical conductivity
  • Improved or maintained mechanical properties
  • Retained color, without carbon release to the surface 
  • Maintained elasticity
  • Standard processing and mixing equipment

To know more about products based on graphene nanotubes that are used in BR, please check the selection guide below and contact us for help in ordering or for additional information. 


TUBALL™ for rubbers

ProductCarrierCompositionTarget systems
NRSBRIRBREPDMNBRHNBRFKMPVC
TUBALL™ MATRIX concentrates (Black flakes paste @ standard dosage 1.5%–6%)
608 betaPolymerFluoro gum + barium sulfate
(CAS-No. 7727-43-7)
matrix 610Polymer + plasticizerPolymer + paraffinic mineral oil
615 betaPolymer + plasticizersPolymer + TDAE oil (distillates (petroleum), solvent refined heavy paraffinic, CAS-No. 64741-88-4) +
hydrocarbon resin
619 betaPolymer + plasticizerPolymer + dibutyl phthalate
(CAS-No. 84-74-2)
620.3 betaPolymer + plasticizerPolymer + TDAE oil (distillates (petroleum), solvent refined heavy paraffinic, CAS-No. 64741-88-4)
621 betaPolymerFluoro gum
622 betaPolymerFluoro gum
623 betaPolymer + plasticizerPolymer + polar solvent


Contact us to discuss your project specifications or to request a TUBALL™ MATRIX sample